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在实验测得连续一级反应的中间体最大浓度[B]_(max)和相应的反应时间 t_(max)的基础上,对其动力学方程进行一系列推导,使二元优化变为一元优化,再利用黄金分割法进行计算机模拟,求得 P—硝基氯苯与氰基乙氧甲酰基甲基碳负离子的亲核取代反应中,电子转移和反应中间体 p—硝基氯苯负离子自由基的分解反应速率常数 k_1和 k_2及相应的活化参数,得到了满意的结果.
Based on the experimentally measured maximum concentration [B] _ (max) and the corresponding reaction time t_ (max) of the continuous first-order reaction, a series of derivations of the kinetic equations were made to make the binary optimization into one yuan Optimization, and then use the golden section method for computer simulation, obtained p-nitrochlorobenzene and cyanoethoxy formyl carbanion nucleophilic substitution reaction, electron transfer and reaction intermediate p-nitrochlorobenzene anion The dissociation rate constants k_1 and k_2 of free radicals and the corresponding activation parameters obtained satisfactory results.