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合成和表征了新型异双核配合物（ｃｕ（ｏｘａｅ）ＭｎＬ２］（ｃｌｏ４）２，ｏｘａｅ表示Ｎ，Ｎ′－双（２－氨乙基）草酰胺根阴离子，Ｌ表示５－硝基－１，１０－邻菲罗啉（ＮＯ＿２·ｐｈｅｎ）。测定了配合物的变温磁化率（４．２～３００Ｋ），并用最小二乘法和从自旋Ｈａｍｉｌｔｏｎｉａｎ算符，导出的磁方程拟合，求得交换积分Ｊ＝一３５．７８ｃｍ一１，表明Ｃｕ（Ⅱ）－Ｍｎ（Ⅱ）双核配合物具有反铁磁超交换作用。
The novel heterodinuclear complex (cu (oxae) MnL2] (clo4) 2 was synthesized and characterized. Oxae represents N, N’-bis (2-aminoethyl) oxalate anion, L represents 5-nitro- 10-phenanthroline (NO 2 · phen) .The magnetic susceptibility (4.2-300 K) of the complex was measured and fitted by the least-square method and the magnetic equation derived from the spin Hamiltonian operator to obtain the exchange The integral J = 35.78cm-1, indicating that Cu (Ⅱ) -Mn (Ⅱ) binuclear complex has antiferromagnetic super-exchange.