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金属有机骨架化合物(Metal-organic Frameworks,MOFs)是由无机金属离子或金属簇与桥连的有机配体通过自组装相互连接,形成的一类具有周期性网络结构的晶态多孔材料[1]。MOFs具有大的比表面积和规整的孔道结构,有利于底物和产物分子的扩散和传输。MOFs成为近十年来研究不衰的领域,一方面是因为研究者可以精准地定制自己所需的MOF,另一方面是其诸如气体吸附,催化等应用前景不断被展示。催化过程一直被视为MOF最有前景的应用领域,但是由于化学稳定
Metal-organic Frameworks (MOFs) are crystalline porous materials with periodic network structure formed by self-assembly of inorganic metal ions or metal clusters and bridged organic ligands [1] . MOFs have a large specific surface area and regular pore structure, which facilitates the diffusion and transport of substrate and product molecules. MOFs has become an unmanageable research field in the last ten years. On the one hand, MOFs can be precisely tailored to the MOFs they need and on the other hand, their applications such as gas adsorption and catalysis have been continuously demonstrated. Catalytic processes have long been regarded as the MOF’s most promising applications, but due to chemical stability