【摘 要】
：
Two new Ni(Ⅱ) coordination polymers,{[Ni(tbip)(bipy)(H2O)]·0.5H2O}n 1 and [Ni(tbip)(phen)(H2O)]n 2(H2tbip=5-tert-butyl isophthalic acid,bipy=2,2′-bipyridine,
【机 构】
：
Department of Chemistry,Zhengzhou University,College of Chemistry and Chemical Engineering,Luoyang N
论文部分内容阅读
Two new Ni(Ⅱ) coordination polymers,{[Ni(tbip)(bipy)(H2O)]·0.5H2O}n 1 and [Ni(tbip)(phen)(H2O)]n 2(H2tbip=5-tert-butyl isophthalic acid,bipy=2,2′-bipyridine,phen=1,10-phenanthroline),have been synthesized under hydrothermal conditions and characterized by elemental analysis,X-ray diffraction,and IR spectroscopy.In the two polymers,H2tbip acts as a tridentate ligand.Compound 1 has a tbip bridged 1-D linear chain which is extended by hydrogen bonds into a 1-D double chain,while compound 2 exhibits a 1-D zig-zag chain.
Two new Ni (Ⅱ) coordination polymers, {[Ni (tbip) (bipy) (H2O)] · 0.5H2O} n 1 and [Ni (tbip) butyl isophthalic acid, bipy = 2,2’-bipyridine, phen = 1,10-phenanthroline), have been synthesized under hydrothermal conditions and characterized by elemental analysis, X-ray diffraction, and IR spectroscopy. the two polymers, H2tbip acts as a tridentate ligand. Compound 1 has a tbip bridged 1-D linear chain which is extended by hydrogen bonds into a 1-D double chain, while compound 2 exhibits a 1-D zig-zag chain.
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