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提出一个简单的相平衡方程描述某些非理想溶液的汽液相平衡关系- 用线性最小二乘法确定方程中的待定系数, 由该方程计算的汽液相平衡组成与实验值较吻合- 将该方程与余国琮和CoullJ方程结合, 可以近似地表示更多的非理想溶液的汽液相平衡关系- 利用该方程导出了计算最少理论板数和最少传质单元数的公式, 并讨论了该方程在精馏计算中的若干应用
A simple phase equilibrium equation is proposed to describe the vapor-liquid equilibrium of some non-ideal solutions. The linear least square method is used to determine the undetermined coefficients in the equation. The equilibrium composition of the vapor-liquid phase calculated by this equation is in good agreement with the experimental data. The equation, in combination with Yu Guocheng and CoullJ equations, can be used to approximate the vapor-liquid equilibrium of more non-ideal solutions. The formula for calculating the minimum theoretical plate number and the mass transfer unit number is derived using this equation. Some applications in distillation calculation