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用滴定量热法研究萃取有机相中反向胶束的形成,分别测定P204(钠)-仲辛醇-煤油体系和季铵盐-仲辛醇-煤油体系的临界胶束浓度、聚集数和胶束形成常数等,并讨论了胶束的形成对萃取分配比的影响。
The formation of reverse micelles in the extracted organic phase was investigated by titration calorimetry. The critical micelle concentration, the number of aggregates and the concentration of P204 (sodium) -saturated octanol-kerosene system and quaternary ammonium salt- Micellar formation constants, etc. The effects of micelle formation on extraction partition ratio were also discussed.