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通过甲酰基二茂铁与相应芳酰基肼的缩合反应合成了二茂铁基的苯甲酰基、对-甲氧基苯甲酰基和间-硝基苯甲酰基腙,并制备了它们与Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)和Mn(Ⅱ)醋酸盐的十种整合物。元素分析、IR和PMR谱的测定结果表明,这些金属有机配体是以烯醇式进行配位的。
The ferrocenylbenzoyl, p-methoxybenzoyl and m-nitrobenzoylhydrazone were synthesized by the condensation reaction of formylferrocene with the corresponding aroyl hydrazines and their coordination with Co ( Ⅱ), Ni (Ⅱ), Cu (Ⅱ) and Mn (Ⅱ) acetate. The results of elemental analysis, IR and PMR spectra show that these metal-organic ligands are enol-typed.