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本文讨论金属离子M~(n+)—H_2O体系中,单核羟基配合物的标准生成自由能变化同金属离子的Z~*/r_(eff)的线性相关性。提出了羟基配合物M(OH)_y~((n-y)+)逐级形成常数的计算公式,计算结果与实验测定值十分近似。
In this paper, the linear dependence of the standard free energy of mononuclear hydroxyl complexes on metal ion M ~ (n +) - H_2O with the Z ~ * / r eff of metal ions is discussed. The calculation formula of successive formation of the hydroxyl complex M (OH) _y ~ ((n-y) +) is proposed. The calculated results are in good agreement with the experimental ones.