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利用扫描隧道显微镜(STM)系统地研究了C60薄膜在GaAs(001)表面的异质外延生长.在GaAs(001)2×4β相表面,观察到C60薄膜以非密排面进行生长,并在生长中有结构相变产生.实验数据表明,薄膜下层面心立方(fcc)的晶格常数比C60晶体的晶格常数要大13%;而薄膜的表层结构则展示了非理想的六角密堆(hcp)结构,其表面为hcp(1100)面,生长过程是非理想的层状生长模式.在GaAs(001)c(4×4)衬底上,C60薄膜的表面仍然是fcc(111)面,其结构参数与C60晶体一致,但C60薄膜采用了三维模式进行生长
The heteroepitaxial growth on the GaAs (001) surface of C60 thin films was investigated systematically by scanning tunneling microscope (STM). On the surface of GaAs (001) 2 × 4β phase, C60 films were observed to grow on non-dense surfaces, and structural phase transitions occurred during growth. Experimental data show that the lattice constant of the fcc in the lower layer of the film is 13% larger than that of the C60 crystal, while the surface structure of the film shows a non-ideal hexagonal close-packed structure with a surface of hcp (1100) surface, the growth process is not ideal lamellar growth mode. On the GaAs (001) c (4 × 4) substrate, the surface of the C60 thin film is still the fcc (111) plane, and the structural parameters are consistent with the C60 crystal. However, the C60 thin film adopts a three-dimensional pattern