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利用Ferrier反应,合成了一类新的含有二糖结构的核苷类似物。通过GCOSY和GNOESY技术归属了所有的质子,并讨论了这类化合物的构型。所得结论与计算机分子模拟结果一致。
Ferrier reaction was used to synthesize a new class of nucleoside analogs with disaccharide structure. All protons are assigned by the GCOSY and GNOESY techniques and the configuration of these compounds is discussed. The conclusion is consistent with the results of computer molecular simulation.