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1980年,Sharpless发现用他的试剂[Ti-(OiPr)_4,(+)-或(-)-酒石酸和叔丁基过氧化氢]可对烯丙醇进行不对称环氧化。以后该反应广泛地应用于许多光学活性天然产物的
In 1980, Sharpless found that allylic alcohols can be asymmetrically epoxidized with his reagent [Ti- (OiPr) 4, (+) - or (-) - tartaric acid and t-butyl hydroperoxide]. The reaction has since been widely applied to many optically active natural products