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在 DMSO溶剂中 ,异核 Pt- Tl金属 -金属键化合物 [(DMSO) x(NC) n Tl- Pt(CN) 5]n- (n=0～ 3)被合成和制备出来。在溶液中 ,应用 2 0 5Tl核磁共振谱系统进行了化合物的结构表征。并对其核磁参数的差别进行了系统分析和讨论
The heteronuclear Pt-Tl metal-metal bond [(DMSO) x (NC) n Tl-Pt (CN) 5] n- (n = 0-3) was synthesized and prepared in DMSO solvent. The structural characterization of the compounds was carried out using a 205 Tl nuclear magnetic resonance spectroscopy system in solution. The differences of NMR parameters were systematically analyzed and discussed