论文部分内容阅读
用最小二乘法拟合ＣＨ３Ｄ分子６４２８ｃｍ－１附近振动带的１３８个能级，１０个振动常数。振动分析阐明该带为ＣＨ３Ｄ分子Ｃ—Ｄ对称伸缩振动３Ｖ２态，并与局域模振动理论计算值进行了比较。
The least squares method was used to fit 138 energy levels and 10 vibrational constants of the vibration band around the CH3D molecule at 6428cm-1. Vibration analysis shows that the band is the 3V2 state of C-D symmetric stretching vibration of CH3D molecule, and is compared with the calculated value of local mode vibration.