论文部分内容阅读
用Ｃｏ２（ＣＯ）８与含硫含磷杂环配体ＣｌＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓反应，合成得到含有半填隙μ６－Ｐ原子的新的六核簇Ｃｏ６（μ６－Ｐ）（μ－ＳＣＨ２ＣＨ２ＣＨ２Ｓ）（μ－ＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓）（ＣＯ）１２１，同时，得到三核簇Ｃｏ３（μ－ＰＳＣＨ２ＣＨ２ＣＨ２Ｓ↓）３（ＣＯ）６２，通过元素分析和波谱表征确定了二个簇合物的分子结构．
A new hexanuclear cluster Co6 (μ6-P) (μ-SCH2CH2CH2S) (μ-PSCH2CH2CH2S) containing half-interstitial μ6-P atoms was synthesized by the reaction of Co2 (CO) ↓) (CO) 121. At the same time, the ternary cluster Co3 (μ-PSCH2CH2CH2S ↓) 3 (CO) 62 was obtained. The molecular structures of the two clusters were determined by elemental analysis and spectral analysis.