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用推广的Solomon方程描述了1H通道加上射频场的13C自旋晶格弛豫.分析表明在1H射频照射下13C自旋晶格弛豫通常是一个三指数过程,但是在一些实验条件下可以变为单指数的;数值计算给出了满足和满足的13C自旅晶格弛豫过程的明显差别.并显示了不同射频场强度的影响.实验观测了固体L-缬氨酸的甲基13C自旋晶格弛豫,所得结果与理论分析很好符合.
The 13C spin-lattice relaxation of the 1H channel plus the radio-frequency field is described by a generalized Solomon equation. The analysis shows that the 13C spin lattice relaxation is usually a triple exponential process under 1 H radio frequency irradiation, but it can be changed into single exponential under some experimental conditions. The numerical calculation gives 13C self-traveling lattice relaxation The obvious difference in the process. And shows the impact of different RF field strengths. The methyl 13C spin-lattice relaxation of solid L-valine was observed experimentally and the results were in good agreement with the theoretical analysis.