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本文研究了异丙苯液相氧化合成CHP混合催化剂NaOH-NaCl的效应。研究结果表明,当0.05%NaOH与0.05%NaCl配伍时,CHP的累积量比单用0.05%NaOH可提高3%左右,而选择性仍可保持在90%。并提出这一催化体系的动力学模型和参数估计。
In this paper, the effect of liquid phase oxidation of isopropylbenzene on the synthesis of NaOH-NaCl was investigated. The results show that when the 0.05% NaOH and 0.05% NaCl compatibility, CHP accumulation than single 0.05% NaOH can be increased by about 3%, while the selectivity can still be maintained at 90%. The kinetic model and parameter estimation of this catalytic system are proposed.