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The two bands of O_1 (~1Δ_g) dimer, whose peak wavelengths are 703 and 634nmrespectively, were first observed by Arnold et al. Then a lot of researches on the spectraof O_2 (~1Δ_g) dimer and the rate constant of reaction O_2+O_2=O_4 were made by manyresearchers. A net gain of 2.8% cm for O_2(~1Δ_g) dimer at 703 nm was first obtained