研究了高价Mg~(2+),Zn~(2+)等离子对层状结构阴极如V_2O_,MoS_,等的固态电化学插入。用X射线衍射(XRD),电子探针微区分析(EMP),电子自旋共振(ESR)和X射线光电子能谱(XPS)等物理方法研究了相应高价离子对层状阴极插入引起的相变及其插入化合物,对高价离子的插入机理进行了探讨。 The solid state electrochemical insertion of layered Mg (2 +) and Zn 2+ ions into layered cathode such as V 2 O 3, MoS 2 and so on was studied. The effects of the corresponding high-valent ions on the phase induced by lamellar cathodic insertion were investigated by X-ray diffraction (XRD), electron probe microanalysis (EMP), electron spin resonance (ESR) and X-ray photoelectron spectroscopy (XPS) Change and its insertion of compounds, high ion insertion mechanism were discussed.