论文部分内容阅读
时至今日,对氧化物玻璃态结构尚没有一个完整、确切的理论,本文是继本人对“无机化合物玻璃态结构”的看法之后,提出对无机氧化物玻璃态结构的看法:氧离子和某些中心阳离子以离子——共价混合键形成络氧负离子,络氧负离子以氧为公共顶点相互联结而构成络氧离子群;络氧离子群尚能和很多种络合阳离子形成可变组成、介稳、巨大的络氧化合物,无机氧化物玻璃的化学式为:A_tB_*C_xD_yE_zO_(t/2+ω+3/2x+2y+5/2z)·M~(p+)·N~(q+)。
Up to now, there is not a complete and exact theory about the glassy structure of oxide. This paper, following my own opinion about the glassy structure of inorganic compounds, puts forward the viewpoints of the glassy structure of inorganic oxides: Some cations in the center form ion-anion covalently and covalently bond to form oxygen anions. The oxygen anions are linked to each other with oxygen as the common vertex to form oxygen-containing ion groups. The oxygen-ion groups can still form a variable composition with many kinds of complex cations, Metastable, huge oxygen compounds, inorganic oxide glass chemical formula: A_tB_ * C_xD_yE_zO_ (t / 2 + ω +3 / 2x +2 y +5 / 2z) · M ~ (p +) · N ~ (q +).