用固体微粒伏安法在电极表面直接获得了铜卟啉、铁卟啉及钴卟啉 ,在氯化钾支持电解质溶液中用循环伏安法对meso 四苯基卟啉 (H2 TPP)及现场合成的金属卟啉的固体电化学行为进行了表征 .作为电荷补偿 ,实验证明在固体金属卟啉还原及氧化过程中同时伴随有钾离子在晶胞中的迁移 ,文中对金属卟啉的形成机理及其电极反应机理进行了详细探讨 . The copper microporphyrins, iron porphyrins and cobalt porphyrins were directly obtained on the surface of the electrode by voltammetry of solid particles. The meso tetraphenylporphyrin (H2 TPP) and the on-site The electrochemical behavior of the synthesized metalloporphyrins was characterized.As a charge compensation experiment, it was proved that the migration of potassium ions in the unit cell was accompanied by the reduction and oxidation of the solid metalloporphyrin. In this paper, the formation mechanism of metalloporphyrin And its electrode reaction mechanism were discussed in detail.