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Sisal filbre is a kind of natural filbre which possesses high specic strength and modu- lus, low price, recycalability, easy availability in some countries. Using sisal filbre as reinforcement to make sisal filbre reinforced polymer composites has aroused great interest of materials scientists and engineers all over the world. Many researches have been done in recent years which include the study of mechanical properties of the composites, nding an ecient way to improve the inter- facial bonding properties between sisal bre and polymeric matrices and bre surface treatment on the mechanical performance of the composites. Though many researches on sisal bre reinforced composites have been done so far, none deals with the fracture properties of this novel composite which is crucial for the actual application of this material. In this research, Charpy impact test and compact tension test were employed to study the fracture toughness of sisal bre reinforced vinyl ester and epoxy composites. The eect of bre surface treatment on the fracture properties of these composites by permanganate and silane was evaluated. The initiation and propagation of the crack were observed with optical microscopy (OM). The fracture morphologies revealed by OM explains the fracture phenomenon of sisal bre reinforced composites.