【摘 要】
：
A novel chiral bis(ferrocenyl) P2N ligand 1 with C2-symmetry was synthesized through a four-step procedure from (R)-N,N-dimethyl-1-ferrocenylethylamine. In a m
【出 处】
：
Chinese Chemical Letters
论文部分内容阅读
A novel chiral bis(ferrocenyl) P2N ligand 1 with C2-symmetry was synthesized through a four-step procedure from (R)-N,N-dimethyl-1-ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1,3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% e.e.) was obtained.
A novel chiral bis (ferrocenyl) P2N ligand 1 with C2-symmetry was synthesized through a four-step procedure from (R) -N, N-dimethyl- 1 -ferrocenylethylamine. In a model reaction of Pd-catalyzed allylic alkylation of 1, 3-diphenylprop-2-enyl acetate 6 with dimethyl malonate, good enantioselectivity (86% ee) was obtained.
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