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离子极化概念是由波兰化学家Fajans率先于1923年提出,起初主要用于解释无机化合物的化学性质和光学性质,收到一定成效。六十多年来,离子极化理论已有较大发展,已成为现代化学键理论中的一种重要学说,并取得一些有意义的半定量或定量成果,它被应用于化学的多个领域,已成为无机化学、结晶化学、结构化学和地球化学等学科的重要内容。近期,又被应用到固体物理学领域。本文旨在讨论离子极化理论中的一些半定量或定量结果。
The concept of ion polarization was first proposed by the Polish chemist Fajans in 1923 and initially primarily used to explain the chemical and optical properties of inorganic compounds and received some success. For more than sixty years, the theory of ion polarization has been greatly developed. It has become an important theory in modern chemical bond theory and has made some meaningful semi-quantitative or quantitative results. It has been applied to many fields of chemistry, Has become an important part of inorganic chemistry, crystallochemistry, structural chemistry and geochemistry. Recently, it has been applied to the field of solid state physics. This article aims to discuss some of the semi-quantitative or quantitative results in ion polarization theory.