综述了近四年来新型超分子主体化合物柱芳烃的合成、发展和应用.其中,柱芳烃及其衍生物的合成主要有两种有机化学合成策略,即“先成环后修饰”和“先修饰后成环”.由于这类新型主体化合物具有非常特殊的空间结构和理化性质,目前,它主要应用在主客体包合与分子识别、自组装体系的构筑和智能材料等领域. The synthesis, development and application of the novel supramolecular compound, aromatics, were reviewed in this paper.Among them, there are two main synthetic methods for the synthesis of p-aromatics and their derivatives, that is, “pre-ring modification” and “ ”The first modified into a ring." Because of these new host compounds have very special spatial structure and physical and chemical properties, at present, it is mainly used in the hostage and inclusion and molecular recognition, self-assembly system construction and intelligent materials and other fields.