新型沸石分子筛的开发是国际上分子筛化学界关注的问题之一。我们为了开拓含杂原子骨架结构的沸石分子筛的合成工作,系统地进行了硼硅Pentasil型沸石的研究。 1980年M.Taramasso等人首次合成了硼硅沸石(Boralite)。我们用四丙基胺氢氧化物,正硅酸乙酯、硼酸等试剂在国内首次合成了硼硅沸石分子筛。它的结构与Pentasi型相似。我们在研究晶化相区的基础上扩大了硼硅沸石的合成条件。在合成Boralite过程中,发现并合成了此种沸石导向剂。在研究由我们首次发现的硼硅沸石导 The development of new zeolite molecular sieve chemistry is one of the concerns of the international community. In order to explore the synthesis of zeolite molecular sieve with heteroatom skeleton structure, we systematically studied the borosilicate Pentasil zeolite. In 1980, for the first time, M.Taramasso et al. Synthesized Boralite. We use tetrapropyl amine hydroxide, TEOS, boric acid and other reagents in the country for the first time synthesis of borosilicate zeolite. Its structure is similar to Pentasi. Based on the study of the crystallization phase region, we expanded the synthesis conditions of borosilicate zeolite. This zeolite directing agent was discovered and synthesized during the synthesis of Boralite. In studying the borosilicate zeolite first discovered by us