Preparation,Characterization and Comparative NH_3-sensing Characteristic Studies of PANI/inorganic O

来源 :Journal of Materials Science & Technology | 被引量 : 0次 | 上传用户:dennaxu
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Polyaniline (PANI), polyaniline/titanium dioxide (PANI/TiO2), polyaniline/tin oxide (PANI/SnO2) and polyani- line/indium oxide ℃(PANI/In2O3) thin films were developed by using an in-situ self-assembly method at ~10℃. Chemical structure, optical property and morphology of all the thin films were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, UV-Vis absorption spectroscopy, scanning electron mi- croscopy (SEM) and transmission electron microscopy (TEM). NH3 gas-sensing properties of PANI and PANI nanocomposite thin films were examined at ambient temperature. The results showed that all the sensors composed of PANI nanocomposite thin films had faster response/recovery rate with better reproducibility, selectivity and long-term stability to NH3 than PANI thin film sensor, and PANI/TiO2 nanocomposite thin film sensor showed optimum NH3 gas-sensing characteristics. The effect of humidity on the responses of all the sensors was also investigated. Polyaniline (PANI), polyaniline / titanium dioxide (PANI / TiO2), polyaniline / tin oxide (PANI / SnO2) and polyani- line / indium oxide (PANI / In2O3) thin films were developed by using an in-situ self- method at ~ 10 ° C Chemical structure, optical property and morphology of all the thin films were characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, UV-Vis absorption spectroscopy, scanning electron microscopy ) and transmission electron microscopy (TEM). NH3 gas-sensing properties of PANI and PANI nanocomposite thin films were examined at ambient temperature. The results showed that all the sensors composed of PANI nanocomposite thin films had faster response / recovery rate with better reproducibility, selectivity and long-term stability to NH3 than PANI thin film sensor, and PANI / TiO2 nanocomposite thin film sensor showed optimum NH3 gas-sensing characteristics. The effect of humidity on the responses of all the sensors was also investigate d.
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