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含磺酸基有机配体的配合物种类繁多,其中主要包括简单磺酸配合物、芳香环磺酸配合物、杂环芳香磺酸配合物和Schiff碱磺酸配合物等。其空间结构多种多样,比如一维链状结构、二维层状结构和三维网状结构。该类配合物具有优异的物理和化学性质,在众多领域里显示出广阔的应用前景。合成结构新颖、组成多样的新型磺酸基配合物及其应用研究已经成为配位化学领域的研究前沿和热点之一。综述了含磺酸基有机配体配合物的分类以及结构研究进展,探讨了该研究领域亟待解决的问题以及今后可能的发展前景。
Sulfonate-based organic ligands with a wide range of complexes, including simple sulfonic acid complexes, aromatic ring sulfonic acid complexes, heterocyclic aromatic sulfonic acid complexes and Schiff base sulfonate complexes. The spatial structure of a variety of, such as one-dimensional chain structure, two-dimensional layered structure and three-dimensional network structure. These complexes have excellent physical and chemical properties, in many fields show a broad application prospects. Synthesis of novel structures, composed of a variety of new sulfonic acid-based complexes and its application research has become the field of coordination chemistry frontier and one of the hot spots. This review summarizes the classification and structure of sulfonic acid-based organic ligand complexes and discusses the problems to be solved in the field of this research as well as the possible future development prospects.