Syntheses and bioactivities of mixed butyl/cyclohexyl tin carboxylates

来源 :Chinese Journal of Chemistry | 被引量 : 0次 | 上传用户:hhtui
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Eight novel compounds have been synthesized and they are two series of mixed tri(butyl/cyclohexyl) tin carboxylates:Bu_nCy_(3-n) SnO_2CR (n=1,2;R=n-C_3H_7,C_6H_5,4-ClC_6H_4,4-NO_2C_6H_4).Inaddition to the studies of their structures with IR,~(119)Sn and ~(13)C NMR,we tested their fungicidal,insec-ticidal and acaricidal activities.The percentage of inhibition to the aforementioned phytopathogen isabout 80—100% at 50 ppm in glasshouse and 100% for T.Uriticae at 500 ppm.Those findingsindicate that this kindof compounds have both fungicidal and acaricidal activities and mayhave a goodprospect for applications. Eight novel compounds have been synthesized and they are two series of mixed tri (butyl / cyclohexyl) tin carboxylates: Bu_nCy_ (3-n) SnO_2CR (n = 1,2; R = n-C_3H_7, C_6H_5,4-ClC_6H_4,4- NO_2C_6H_4). Addition to the studies of their structures with IR, ~ (119) Sn and ~ (13) C NMR, we tested their fungicidal, insec- ticidal and acaricidal activities. The percentage of inhibition to the phytopathogen isabout 80-100 % at 50 ppm in glasshouse and 100% for T. Uriticae at 500 ppm. Thhough findingsindicate that this kind of compounds have both fungicidal and acaricidal activities and mayhave a good prospect for applications.
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