采用离子交换法,以锌铝碳酸根型水滑石(Zn/AlCO3LDHs)为前体,进行了钼系络离子[O{MoO(O2)2}2]2-插层水滑石的研究,利用X射线衍射(XRD)、红外光谱(FTIR)和元素分析等手段对插层产物结构和组成进行了分析。结果表明:离子交换法可制备出钼系络离子[O{MoO(O2)2}2]2-插层Zn/AlCO3LDHs的产物,插层产物保持了原有水滑石的层状结构,而且升高温度有利于层间阴离子交换完全,从而使晶体结构趋于完整。 The ion exchange method was used to study the molybdenum complex ion [O {MoO (O2) 2} 2] 2-intercalated hydrotalcite with Zn / AlCO3LDHs as precursor. Ray diffraction (XRD), infrared spectroscopy (FTIR) and elemental analysis of the structure and composition of the intercalated products were analyzed. The results show that the ion exchange method can be used to prepare the product of molybdenum series ion [O {MoO (O2) 2} 2] 2-intercalated Zn / AlCO3LDHs. The intercalation product maintains the original layered structure of hydrotalcite, The high temperature is conducive to the anion exchange layer completely, so that the crystal structure tends to be complete.