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按照下列反应曾合成八种 O,O-二烷基三硫代过氧磷酸硝苯基酯。(?)R=CH_3,C_2H_5(?),或 i-C_3H_7(?)(?)这反应进行十分顺利,一般收获率可达90%。虽然这类化合物在结构上与 E-605及其类似物很相近,但其杀虫能力很低,可见三硫代过氧磷酸酯与硫代磷酸酯不同,缺乏杀虫能力。O,O-二烷基三硫代过氧磷酸酯在固态时很稳定,但在乙醇中回馏或在140—150°时熔融,则分解为双硝苯基二硫物及其他分解产物。
Eight kinds of O, O-dialkyltrithio-hydroperoxide phosphonates were synthesized according to the following reaction. (?) R = CH_3, C_2H_5 (?), Or i_C_3H_7 (?) (?) The reaction proceeded smoothly with a typical yield of 90%. Although these compounds are similar in structure to E-605 and its analogs, its insecticidal activity is very low. Thus, trithioperoxyphosphates, unlike thiophosphates, lack pesticidal activity. O, O-dialkyl trithioperoxophosphates are very stable in the solid state, but are either back-distilled in ethanol or melted at 140-150 ° C, decomposing into dinitrophenyl disulfides and other decomposition products.