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A novel one-dimensional chain-like coordination polymer constructed from 3-nitro- benzene-1,2-dicarboxylic acid, [Cd2(C8H3NO6)2(H2O)4]n·2nH2O, has been synthesized and its structure was determined by X-ray crystallography method. The crystal belongs to monoclinic, space group P21/c with a = 6.1252(8), b = 20.706(3), c = 8.8067(11) , β = 95.608(2)°, V = 1111.6(2) 3, Mr = 751.12, Dc = 2.244 g/cm3, F(000) = 736, μ = 2.011 mm-1, Z = 2, the final R = 0.0262 and wR = 0.0692 for 2338 observed reflections with I > 2σ(I). The structure of the title compound presents a 1-D chain-like structure constructed by dimer units, [Cd2(C8H3NO6)2(H2O)4]n, through two carboxylate oxygen atoms. The fluorescence of the title compound has been also discussed in this paper.
A novel one-dimensional chain-like coordination polymer constructed from 3-nitro-benzene-1,2-dicarboxylic acid, [Cd2 (C8H3NO6) 2 (H2O) 4] n · 2nH2O, has been synthesized and its structure was determined by X The crystal belongs to monoclinic, space group P21 / c with a = 6.1252 (8), b = 20.706 (3), c = 8.8067 (11) , β = 95.608 (2) °, V = 1111.6 (2) Mr3, Mr = 751.12, Dc = 2.244 g / cm3, F (000) = 736, μ = 2.011 mm- 1, Z = 2, the final R = 0.0262 and wR = 0.0692 for 2338 observed reflections with I > 2σ (I). The structure of the title compound presents a 1-D chain-like structure constructed by dimer units, [Cd2 (C8H3NO6) 2 (H2O) 4] n, through two carboxylate oxygen atoms. compound has been covered in this paper.