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分析了Thodos等人的理论及公式的缺点后,利用分子物理学和光谱学的理论与实验研究数据,根据Van der Vaals方程及数学分析导出了公式T_e=T_b/(0.580+K+K~2+K~4)。对29类234种纯物质进行计算,平均误差为0.54％,优于文献中各式。
After analyzing the shortcomings of the theory and formula of Thodos et al., The theoretical and experimental data of molecular physics and spectroscopy are used to derive the formula T_e = T_b / (0.580 + K + K ~ 2) according to Van der Vaals equations and mathematical analysis + K ~ 4). The calculation of 29 pure substances of 234 kinds with an average error of 0.54% is superior to all kinds of literature.