【摘 要】
：
The hybrid Au(Ⅰ)/Bransted acid binarycatalyst system enables enynes to serve as latent 1,3-silyloxydienes capable of participating in the first cascade hydrosiloxylation of an enynylsilanol/asymmetric
【机 构】
：
Hefei National Laboratory for Physical Sciences at the Microscale and Department of Chemistry,Univer
【出 处】
：
The 24th International Society of Heterocyclic Chemistry Con
论文部分内容阅读
The hybrid Au(Ⅰ)/Bransted acid binarycatalyst system enables enynes to serve as latent 1,3-silyloxydienes capable of participating in the first cascade hydrosiloxylation of an enynylsilanol/asymmetric Aza-Diels-Alder reaction.A variety of polycyclic compounds bearing multistereogenic centers were obtained in yields and good enantioselectivities from the relay catalytic cascade reaction between (2-(but-3-en-1-ynyl)phenyl) silanols and glyoxylate catalyzed by the combined achiral gold complex and chiral N-triflylphosphoramide.
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