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The structural condition of solidifying binding system has various thermodynamic stability and the degree ot ordering.It predetermines the tendency of these systems to self-organizing.Self-organizing of binding system can be considered as a process of originating and formation of more and more complex space-temporary structures in it, formed by contacts of various nature.The acceleration of hydration after the ending of induction period results in the formation of coagulation-condensation contacts, and it is accompanied by the increase of redundant entropy production.Therefore, it results in the infringement of thermodynamic stability of binding system.