polyoxometalates相关论文
四溴双酚A(TBBPA)是一种重要的塑料添加剂和阻燃剂,广泛用于树脂、塑料、胶黏剂以及涂料中.它不仅是持久性的机污染物,还是一种内......
Self-assembly of a new 3D platelike ternary-oxo-cluster:An efficient catalyst for the synthesis of p
A new metal-oxo-clusters-based inorganic framework[NaCo2Mo2O7(OH)3]n (NaCoMo),named as 3D platelike ternary-oxo-cluster,......
Hierarchical micro-nanostructures from polyoxometalates and polydopamine:Characterization,electroche
Hybrid composite materials with hierarchical structures have attracted continuing attention for their enhanced features ......
能源危机和环境污染已成为影响全人类的严峻问题,太阳能驱动水分解制备清洁可再生的氢能是解决以上问题的有效途径之一,因此,近年......
Two Polyoxometalate-based Host-guest Compounds:Synthesis,Crystal Structure and Catalytic Performance
Two polyoxometalate-based host-guest compounds,(HL1)2(HPW12O40)·～11H2O (1),(HL2)3(PW12O40)·3H2O (2) (L1 =guanine,L2 =2-......
We report an exclusively tandem C—O and C—C bond forming beyond the esterification and cyclization reaction of 2-acylb......
Polyoxometalates-engineered hydrogen generation rate and durability of Pt/CNT catalysts from ammonia
Heterogeneously catalyzed hydrolytic dehydrogenation of ammonia borane is a remarkable structure sen-sitive reaction.In ......
In-situ Immobilization of a Polyoxometalate Metal-Organic Framework (NENU-3) on Functionalized Reduc
Detection of hydrazine originated from electrochemical media has recently gained considerable attention in the sensing f......
Catalytic oxidative desulfurization of fuels in acidic deep eutectic solvents with [(C6H13)3P(C14H29
Deep eutectic solvents (DESs) are a new class of green solvents analogous to ionic liquids due to their biodegradable ca......
Polyoxometalates (POMs) are a class of well-defined transition metal-oxide nanoclusters and have potential applications ......
A series novel inorganic tri-component nanohybrid was fabricated by using polyoxometalates (POMs) as both building block......
Insights into Working Mechanism of Cathode Interlayer in Polymer Solar Cells via [(C8H17)4N]4[SiW12O
A low-cost( 90%),alcohol soluble surfactantencapsulated polyoxometalate complex [(C8H17)4N]4[SiW12O40] has been synthesi......
Combustible agricultural waste is a potential source of energy because of its high organic con-tent and heating value.As......
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Polyoxometalate-based dyes containing double D-π-A chains for p-type dye-sensitized solar cells (DSS
Aseries of polyoxometalate-based p-type DSSCs containing double D-π-A chains weredesigned.The electronic structures,abs......
在水热条件下合成了一种新颖的化合物 [Cu(bime)]4(SiW12O40)1 (bime =1,2-bis(imidazol-1’-yl)ethane,通过元素分析、IR、TG和X......
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Theoretical exploration on switchable NLO response induced by redox properties of polyoxometalates [
The quantum calculations based on density functional theory(DFT)have been carried out to investigate the relationship be......
In recent years,organic-inorganichybridpolyoxometalates(POMs)haveattractedincreasingattention duetotheirdiversestructura......
Hierarchically porous polyoxometalate-based metal-organic frameworks with high stability and improve
A facile and common solvent template strategy for the synthesis of hierarchically micro-and mesoporous polyoxometalate-b......
The electronic structures,electronic circular dichroism(ECD)and UV-visible(UV-vis)absorption spectra of chiral Dawson-ty......
Synthesis and electrocatalytic property of two sandwich-typepolytungstocobaltate(-zincate)modified b
Two new sandwich-typepolyoxometalatesmodified by open-chain carboxyethyltin groups andtransitionmetals,namely[CN3H6]10[(......
Effect of titanium-substituted Keggin-type polyoxometalates on photoconductivity of TiO2/POM nanocom
Photoconductivity of semiconducting materials mainly depends on the free carrier concentrations which rest with the comp......
Connecting carbon nanotubes to polyoxometalate clusters for engineering high-performance anode mater
Carbon nanotubes(CNTs)possess excellent structural and electronic properties and have been widely investigated as anode ......
Design and Synthesis Heteropolyacid Modified Hybrid Material CNTs@MOF-199 Catalyst by Different Meth
The supported catalysts of Mo16V2 loaded with CNTs@MOF-199 are produced via three means including microwave method(CNTs@......
One novel hybrid compound based on [AlW12O40]5-heteropolyanions and cobalt coordination polymer with
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Over the past decade,there are a number of papers published concerning the PO43-templated porous crowntype polyoxometala......
Pyramidal Heteroanion-directed and Reduced MoV-driven assembly of Multi-layered Polyoxometalate Cage
The fabrication of redox-active polyoxometalates(POMs)that can switch between multiple states is critical for their appl......
A theoretical design and investigation on polyoxometalate-based organic-inorganic hybrids for dye-se
Dye-sensitized solar cells(DSSCs)have attracted increasing attention for their ability,which can convert solar light to ......
Interpenetration metal-organic network is one kind of supramolecular polymers with permanent mechanical interlock struct......
Here we present a new approach to molecular-crystals using inorganic polyoxometalate anionic ring-shaped molecules to as......
A novel two-dimensional solid, [{Cu(en)2}4(H4w12O42)]·9H2O (en =ethylenediamine), has been prepared under mild hydrothe......
Main observation and conclusionrnThe development of bifunctional catalysts has drawn much attention in realizing efficie......
Acid catalysis,one of the most important industrial processes,suffers from the toxicity,corrosion and recyclability prob......
Discretepolynuclear clusters have attracted significant interest in the pastdecades because of their intriguing vari......
Catalytic asymmetric epoxidation holds a prominent place in asymmetric catalysis due to the fundamental importance o......
The Two-electron reduced Basket-like [Sr(∈)P6MoⅤ4MoⅥ14O173]8-Polyoxoanion Modified with {Ni(4,4-bipy
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采用溶胶一凝胶与溶剂热相结合的方法制备了系列介孔复合光催化剂SO^2-4-H3PW12O40/TiO2（P123），并对其进行了表征和分析。Nz吸附表面......
采用浸渍法将H3PW12O40负载在ZrO2-WO3上,通过H2O2溶液的敏化,制得H3PW12O40/ZrO2-WO3（x）光催化剂。然后以光降解甲基橙为探针反应,......
Polyoxometalates (POMs),a class of discrete anionic metal oxides in groups V and VI,are constructed via the con- densati......
