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锑矿的发现,约于公元前18世纪在匈牙利发现的小锑块,但在很长时间,人们并未真正地认识这种金属。1556年德国冶金学者阿格里科拉(G.Agricola)在其著作中叙述了用矿石熔析生产硫化锑的方法,但将硫化锑误认为锑。1604年德国人瓦伦廷(B.Valentine)记述了锑与硫化锑的提取方法。18世纪已用焙烧还原法炼锑,1896年制出电解锑。1930年以后,锑矿鼓风炉熔炼法成为生产金属锑的重要方法。上世纪60~70年代发展了多种挥发熔炼和挥发焙烧方法。中国是世界上发现、利用锑矿较早的国家之一。据《汉书食货志》记载:“王莽居摄,变汉制,铸作钱币均用铜,淆以连锡”。《史记》记载:“长沙出连锡”。秦墓出土文物的秦代箭,经光谱
The discovery of the antimony mine was found in small antimony found in Hungary in the 18th century BC, but for a long time people did not really recognize the metal. In 1556 G. Agricola, a German metallurgist, described in his book a method for the production of antimony sulfide from ore by flotation but mistaking it for antimony. In 1604 the German Valentine (B.Valentine) describes the antimony and antimony sulfide extraction method. Antimony was roasted and reduced in the 18th century, and electrolytic antimony was made in 1896. After 1930, the antimony mine blast furnace melting method has become an important method of producing metallic antimony. 60 to 70 years of last century developed a variety of volatile melting and volatile roasting methods. China is one of the countries in the world that discovered and used antimony ore earlier. According to “Han Shi Foodstuffs” records: “Wang Mang Ju photo, change Han system, coins are used for casting copper, confused with the tin.” “Historical Records” records: “Changsha out of tin”. Qin tomb unearthed relics of the Qin Dynasty, the spectrum