Novel acid initiators for the rapid cationic polymerization of styrene in room temperature ionic li

来源 :中国科学：化学英文版 | 被引量 : 0次 | 上传用户：jimmyhill

【摘要】

：

苯乙烯的 Cationic 聚合在房间温度用几个新奇酸的开始者被完成了在温和反应条件到下面的离子的液体(IL ) 与狭窄的多分散性获得低分子的重量的聚合物。两强壮的 protic 酸象

【作者】

：

VIJAYARAGHAVAN R. MACFARLANE D

【机构】

：

DepartmentofChemistry

【出处】

：

中国科学：化学英文版

【发表日期】

：

2012年8期

【关键词】

：

室温离子液体阳离子聚合引发剂苯乙烯小说聚合反应分子量分布低分子量 cationic polymerization HTFSA HBOP IL

【基金项目】

：

The authors thank Australian Research Council and Centre for Green Chemistry, Monash University for the research grants. The authors also thank Masahiro Yoshizawa for providing HTFSA sample.

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苯乙烯的 Cationic 聚合在房间温度用几个新奇酸的开始者被完成了在温和反应条件到下面的离子的液体(IL ) 与狭窄的多分散性获得低分子的重量的聚合物。两强壮的 protic 酸象二度(trifluoromethanesulfonyl ) 那样酰胺酸(HTFSA ) 和象 bisoxalato 那样的中等弱的酸磷的酸(HBOP ) 作为开始者被学习了。HTFSA 开始在房间温度并且在下面很快平的聚合，这被观察了，作为与生产的 HBOP 相比，要求的更慢的聚合提高了温度完成。在开始者的反应的相对差别在他

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