碳/碳复合材料表面声电沉积磷灰石动力学研究

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采用声电沉积技术,在碳/碳复合材料表面制备了生物活性磷酸钙涂层。扫描电镜、X射线衍射、红外反射以及X射线能谱分析表明所制涂层呈现网状结构,其由钙磷比为1.64、含碳酸根的羟基磷灰石组成。根据扫描电镜观察,描述了磷灰石的形成过程。羟基磷灰石的沉积过程可简化为两步——钙磷离子向碳/碳阴极表面运动和羟基磷灰石在碳/碳表面生长。基于此描述,导出了羟基磷灰石沉积动力学公式,并且发现,沉积过程受扩散控制,扩散活化能是30.3kJ/mol.
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