Synthesis of Schiff Base Calix[4]arene Crowns

来源 :中国化学快报 | 被引量 : 0次 | 上传用户:aa377059590
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
This letter reports the synthesis of Schiff base calix[4]arene crowns containing m-xylylene phenol subunit, in which calix[4]arene Schiff base crowns 2a, 2b and 2c were formed by 1:1 condensation of calix[4]arene diamine 1 with dialdehydes (2, 6-diformyl-4-chlorophenol 3a, 2, 6-diformyl-4-methylphenol 3b, 2, 6-diformyl-4-tert-butylphenol 3c) under high dilute condition in refluxing anhydrous ethanol in 65-70% yield.
其他文献
The Zn-Cu(Ⅰ)/HMCM-41 catalysts were successfully prepared in laboratory scale by solid-state ion exchange with CuCl salt, together with introduction of Zn to i
Two novel diterpenes, Euphorprolitherin A (1) and Euphorprolitherin B (2), were isolated from the roots of Euphorbia prolifera. Their structures were elucidated
A novel nano-SnO2/graphite electrode has been prepared via polishing procedure to produce active and stable surface. The modified electrode resolves the overlap
The optimal velocity model of traffc is extended to take the relative velocity into account. The traffcbehavior is investigated numerically and analytically wit
Statistical behavior of a classical φ4 Hamiltonian lattice is investigated from microscopic dynamics. Thelargest Lyapunov exponent and entropies are considered
The effective action of chiral QCD2 was studied in two-dimensional non-commutative space-time by usingpath integral approach. It is shown that vector boson has
(±)-Inophyllum B has been synthesized for the first time by a five-step approach from phloroglucinol, including the Pechmann reaction, Friedel-Crafts acylation
This article shows that in spherical polar coordinates, some noncentral separable potentials have super-symmetry and shape invariance in the r and θ dimensions
The potential energy surface for the CH3S + NO2 reaction has been studied using the ab initio G3 (MP2) method. A variety of possible complexes and saddle points
A new 10-hydroxyl anthrone glycoside, 1, 8, 10 - trihydroxyl-1-O-β-D-glucopyrano-syl-3-methyl-10- C (S) - β - D- glucopyranosyl-anthrone-9 1 was isolated from