Statistical behavior of a classical φ4 Hamiltonian lattice is investigated from microscopic dynamics. Thelargest Lyapunov exponent and entropies are considered for manifesting chaos and equipartition behaviors of the system.It is found, for the first time, that for any large while finite system size there exist two critical couplings for the transitionsto equipartitions, and the scaling behaviors of these lower and upper critical couplings vs. the system size are numericallyobtained.