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Solid-liquid extraction of gadolinium was investigated from phosphoric acid medium using commercial amino phosphonic acid resin, Tulsion CH-93. The experimental conditions studied included equilibration time, acid concentration, mass of the resin, metal concentra-tion, loading and elution. The percent extraction of Gd(Ⅲ) was studied as a function of phosphoric acid (0.05-3 mol/L) using Tulsion CH-93 resin. The corresponding lgD vs. equilibrium pH plot gave straight line with a slope of 1.8. The percent extraction decreased with acid con-centration increasing, conforming ion exchange mechanism. Under observed experimental conditions the loading capacity of Tulsion CH-93 for gadolinium was 10.6 mg/g. Among several eluants screened, the quantitative elution of Gd(Ⅲ) from loaded Tulsion CH-93 was obtained with ammonium oxalate (0.15 mol/L). The extraction behavior of commonly associated metals with gadolinium was studied as a function of phosphoric acid concentration. Tulsion CH-93 resin showed selective extraction towards heavy rare earths (Lu and Yb) which could be sepa-rated from other rare earths at 3 mol/L H3PO4, similar to wet phosphoric acid (3-5 mol/L). On the other hand Gd(Ⅲ) and other rare earths were studied with chelating resin Tulsion CH-90. Light rare earths were highly extracted and these could be separated from heavy rare earths and Gd.)
Solid-liquid extraction of gadolinium was investigated from phosphoric acid medium using commercial amino phosphonic acid resin, Tulsion CH-93. The experimental conditions studied included equilibration time, acid concentration, mass of the resin, metal concentra tion, loading and elution. The The corresponding lgD vs. equilibrium pH plot gave straight line with a slope of 1.8. The percent extraction was obtained as a function of phosphoric acid (0.05-3 mol / L) using Tulsion CH-93 resin. decreased with acid con-centration increasing, conforming ion exchange mechanism. Under observed experimental conditions the loading capacity of TROL CH-93 for gadolinium was 10.6 mg / g. Among several eluants screened, the quantitative elution of Gd (III) from loaded Tulsion CH -93 was obtained with ammonium oxalate (0.15 mol / L). The extraction behavior of commonly associated metals with gadolinium was studied as a function of phosphoric acid concentration. Tulsion CH-93 res in showed selective extraction towards heavy rare earths (Lu and Yb) which could be sepa-rated from other rare earths at 3 mol / L H3PO4, similar to wet phosphoric acid (3-5 mol / L) Ⅲ) and other rare earths were studied with chelating resin Tulsion CH-90. Light rare earths were highly extracted and these could be be separated from heavy rare earths and Gd.)