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制备了有机 -无机杂化材料 (C3H5N2 ) 4PMo Mo 1 1 O4 0 · 4DMF· 2 H2 O.用元素分析、红外光谱和 X射线衍射对其进行了表征 ,该晶体属三斜晶系 ,P1空间群 ,晶胞参数为 a=1 .2 42 3 (3 ) nm,b=1 .2 666(3 )nm,c=1 .3 3 41 (3 ) nm,V=1 .742 3 (6) nm3,α=70 .5 6(3 )°,β=71 .1 6(3 )°,γ=64.1 8(3 )°,Z=1 ,R1 =0 .0 5 85 ,w R2 =0 .1 885 .结构解析表明 ,十二钼磷酸阴离子和质子化的咪唑分子通过静电引力和氢键相互作用 .采用 MTT法 ,对其体外抗前列腺癌活性及毒性进行了研究
The organic-inorganic hybrid material (C3H5N2) 4PMoMo1 1 O4 0 · 4DMF · 2 H 2 O was characterized by elemental analysis, infrared spectroscopy and X-ray diffraction. The crystal belongs to the triclinic system. The P1 space Group, the unit cell parameters are a = 1.242 3 (3) nm, b = 1.2666 (3) nm, c = 1.3331 nm, V = 1.742 3 (6) nm 3, α = 70.56 (3) °, β = 71 .1 6 (3) °, γ = 64.1 8 (3) °, Z = 1, R1 = 0. 0585, w R2 = 0. 1 885. Structural elucidation shows that dodecyanophosphate anion and protonated imidazole molecule interact with each other via electrostatic attraction and hydrogen bonding. The anti-prostate cancer activity and toxicity in vitro were studied by MTT assay