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高效毛细管电泳(HPCE)在手性拆分中的应用近年来受到普遍关注.除最常见CD-CZE体系外,拆分剂为非CD_s类化合物以及非CZE模式的一些拆分体系也非常活跃.本文拟对手性拆分中的非CD-CZE体系做一综述,探讨了各体系的拆分机理,以及各实验条件对拆分结果的影响.
The use of high performance capillary electrophoresis (HPCE) in chiral resolution is of general interest in recent years, and some of the resolution systems for non-CD_s compounds and non-CZE modes are very active in addition to the most common CD-CZE systems. This paper intends to review the non-CD-CZE system in chiral resolution, and discusses the mechanism of disassembly and the influence of each experimental condition on the resolution results.