从计入分子振转相互作用的电子态波函数出发，按自编程序计算了高温空气中主要分子带系O2（S－R），N2（1+），N2（2+），N(2+)（1-），NO（β），NO（λ）的F－C（Franck-Condon）。从而得出：当激液管低压端的空气压强为1333Pa时，入射激波及反射激波后高温空气的温度与微波强度的关系；各主要分子带系转动态分布与温度的关系；高温空气中主要分子带系F－C因子与激波强度的关系。计算结果甚好，它既适用于高温，也适用于低温情况下空气中主要分子的辐射问题。 Based on the electronic state wave function which takes into account the molecular vibrational interaction, the main molecular band systems of O2 (S-R), N2 (1 +), N2 (2 +) and N +) (1 -), NO (β), NO (λ) F-C (Franck-Condon). The results show that when the air pressure at the low pressure side of the liquid pipe is 1333 Pa, the relationship between the temperature and the microwave intensity of the incident airwaves and the reflected shockwaves, the relationship between the rotational distributions of the main molecular bands and the temperature, Relationship Between F-C Factor and Shock Intensity in Molecular Bands. The calculation results are very good, it is suitable for both high temperature and low temperature radiation of the main molecules in the air.