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REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICP-MS after preconcentration. The REE abundances in 26 sulfide samples (including pyrite, galena and sphalerite) are very low, with theεREE ranging from 1.6×10-9 to 166.8×10-9. Their LREE/HREE ratios range from 7.6 to 98, showing LREE enrichment relatively. TheδEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. Similar to the ore-hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly suggest that the ore metals were mainly sourced from carbonate strata.
REE abundances in sulfides from the Huize Zn-Pb ore field were determined with the ICP-MS after preconcentration. The REE abundances in 26 sulfide samples (including pyrite, galena and sphalerite) are very low, with the εREE ranging from 1.6 × 10-9 to 166.8 × 10-9. Their LREE / HREE ratios range from 7.6 to 98, showing that LREE enrichment was relatively lower. The δEu values are below 1, indicating that they were deposited from an Eu-depleted and reducing fluid-system. hosting carbonate strata, calcite separates from carbonate veinlets filling in the fractures or faults crosscutting the carbonate strata also show clear Eu-depletion. This indicates that the carbonate veinlets and their parent fluid was possibly sourced from the strata and inherited the REE geochemical features of the strata. Therefore, REE-geochemical characteristics of both the sulfides and calcites, which were deposited from an ore-forming hydrothermal system, are similar to those of carbonate strata, and strongly su ggest that the ore metals were mainly sourced from carbonate strata.