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研究了以Co(Ⅱ)络合物为催化剂 ,α_卤代萘与叔己酮碳负离子的自由基链式亲核取代反应(SRN1)产物α_萘基叔己酮的薄层色谱扫描定量分析方法 ;定量分析的线性范围为0～4.4μg,平均回收率99 %～101 %,异板间相对标准偏差为2.3 %,同板相对标准偏差为1.6 %。
In this paper, the thin layer chromatographic scan of α-naphthyl tert-hexanone, a free radical chain nucleophilic substitution reaction (SRN1) of α-halogenated naphthalene and tert-hexanone carbanion with Co (Ⅱ) The linear range of quantitative analysis was 0-4.4 μg with an average recovery of 99% -101%. The relative standard deviation (RSD) was 2.3%. The relative standard deviation of the same plate was 1.6%.