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A 2D coordination polymer built by sodium ion and water-soluble p-sulfonato-thiacalix[4]arene of trivalent yttrium complex [Na(H2O)2Y(H2O)6(DMF) (p-sulfonatothiaca lix[4]are-ne)]·9H2O is reported. The complex belongs to the monoclinic system, space group P21/c, with a = 16.703(3), b = 17.819(4), c = 17.357(4) , β = 106.23(3)°, Z = 4, V = 4960.0(17) 3, Mr = 1304.08, Dc = 1.746 g/cm3, μ = 1.624 mm-1, F(000) = 2688, the final R = 0.0398 and wR = 0.1132 for 7534 observed reflections with I > 2σ(I). One yttrium(III) ion is coordinated by the thiacalixarene ligand via the sulfonato group, and also ligated by an oxygen atom of a DMF molecule occupying the cavity of thiacalixarene and six aqua ligands.
A 2D coordination polymer built by sodium ion and water-soluble p-sulfonato-thiacalix [4] arene of trivalent yttrium complex [Na (H2O) 2Y (H2O) 6 (DMF) (p- sulfonatothiaca lix [4] are-ne) ] · 9H2O is reported. The complex belongs to the monoclinic system, space group P21 / c, with a = 16.703 (3), b = 17.819 (4), c = 17.357 , Z = 4, V = 4960.0 (17) 3, Mr = 1304.08, Dc = 1.746 g / cm3, μ = 1.624 mm -1, F (000) = 2688, the final R = 0.0398 and wR = 0.1132 for 7534 at reflections with I> 2σ (I). One yttrium (III) ion is coordinated by the thiacalixarene ligand via the sulfonato group, and also ligated by an oxygen atom of a DMF molecule occupying the cavity of thiacalixarene and six aqua ligands.