论文部分内容阅读
本文阐明了用群论方法确定同一空间构型不同的中心原子的杂化方式;同一配合物假定有不同的空间构型时,通过预言在红外光谱中出现的谱带数,从而可推断结构;根据对称性低的顺式比对称性高的反式配合物红外光谱复杂区分顺反异构体;也可根据单合和二合配体所属点群不同,预言在红外光谱中出现的谱带数不同区分单合和二合配体。
In this paper, the method of group theory is used to determine the hybridization of different central atoms in the same spatial configuration. When the same complex is assumed to have different spatial configurations, the structure can be deduced by predicting the number of bands appearing in the infrared spectrum. According to the low symmetry of the cis symmetric high trans complex infrared spectroscopy complicated cis-trans isomers; also can be based on the singular and bicomponent groups belonging to different points, predicted in the infrared spectrum bands Several different distinction between single and double ligands.