Nitrogen-doped holey graphene nanoscrolls for high-energy and high-power supercapacitors

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Porous structure and heteroatom doping are two key parameters for significantly boosting the capacitive performance of graphene-based materials.Herein,we report a facile approach to prepare onedimensional (1D) nitrogen-doped holey graphene nanoscrolls (NHGNSs) through cold quenching treatment of two-dimensional graphene oxide sheets,followed by thermal annealing in the successive atmosphere of NH3 and air.Benefiting from the synergy of the unique 1 D tubular morphology,abundant nanoholes and nitrogen doping,the NHGNSs exhibit a high specific capacitance of 126 F/g at 1 A/g in ionic liquid electrolyte and excellent rate capability with 81% of the capacitance retained at 20 A/g.Furthermore,the fabricated symmetric supercapacitors based on NHGNSs achieve both high energy density of 53.5 Wh/kg at 875 W/kg and high power density of 17.5 kW/kg at 43.4 Wh/kg.The simple synthetic process and superior electrochemical performance suggest the great potential of NHGNSs for supercapacitor application.
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