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自100°到420°溫度范围内,二氧化氮对氯化氢和溴化氢的氧化反应已作了研究。二者反应牵連到的总的化学反应計算式为NO_2+2HXNO+H_2O+X_2其中HX是HCl或HBr,X_2是Cl_2或Br_2,反应速度随着反应物的浓度而改变,如方程式所示:—d(NO~2)/dt=K_X(HX)(NO_2)。两个比反应速度随着温度而变化,可以概括为
The oxidation of hydrogen chloride to hydrogen bromide by nitrogen dioxide has been studied from 100 ° to 420 ° C. The total chemical reaction implicated in the reaction is NO 2 + 2HXNO + H_2O + X_2 where HX is HCl or HBr and X_2 is Cl_2 or Br_2. The reaction rate changes with the reactant concentration as shown in the equation : -d (NO ~ 2) / dt = K_X (HX) (NO_2). The two reaction rates vary with temperature and can be summarized as